Go into device manager and "Scan for new Devices" to see an insertion or ejection. \f1 The CF cards use a hard disk IDE driver that does not expect hot plugging. Sonnet is developing an update that will allow hot plug.
You need to download and install the Sony SxS UDF Driver, available here http://pro.sony.com/bbsc/ssr/cat-recmedia/resource.downloads.bbsccms-assets-mkt-recmedia-downloads-upgrades.shtml
This is a Microsoft Windows driver bug with some 64GB CF cards. Sonnet is working with Microsoft to resolve this issue. (64GB and 128GB CF cards work fine with Qio and Qio-CF in OS X.)
A partial list of cards Sonnet has tested:
Patriot Pro CF 266x 64GB/128GB card is recognized under Windows
Lexar Pro 1000x UDMA 7 64GB/128GB card reports itself as 32GB
SanDisk Extreme Pro UDMA 6 64GB/128GB card reports itself as 32GB